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You can fly direct to Split with many carriers:

Flight Options to Ljubljana

Easy Jet (Stansted)
Wizz Air (Luton)
Easy Jet (Luton)
Easy Jet (Gatwick)

You can fly direct to Zagreb and arrange transfers to Ljubljana. Duration is just over an hour.

Flight Options to Zagreb (London Stansted) (London Heathrow)

You can fly direct to Venice with many carriers. Then drive to Ljubljana

Flight Options to Venice (Heathrow) (Luton) (London Gatwick) (Manchester, Leeds, Newcastle, Edinburgh & Belfast) (Birmingham) (Birmingham, Manchester) (Gatwick)

You can fly direct to Trieste, then drive to Ljubljana. It's a very scenic journey. Some guests enjoy pre & post stays in Trieste.

Flight Options to Trieste (Stansted)